- 252.3 g/mol
- Polycyclic aromatic hydrocarbons (PAH)
Compound properties list
|Melting/boiling point|| 216 °C||Solid|
|Relative density||0 g/cm3||N/A|
|Vapour pressure||1 x 10 -10 mm Hg||Very low volatility|
|Solubility in water||0.001 mg/L||Very low solubility|
|Henry's law constant||4 x 10-7 atm·m3/mol||Slow volatilization when dissolved|
|log Koc (Depending on soil or sediment characteristics)||6.0 - 7.4*||Very strong adsorption to organic matter|
At 20 0C, benzo(k)fluoranthene is a solid with very low volatility. Characterized by its
very low solubility, it will volatilize slowly once dissolved and adsorbs very strongly to organic
matter. When present in soil, this compound will volatilize and solubilize very slowly. Once
dissolved, it will either enter into the groundwater table or migrate towards a waterway, where it
will be diluted before slowly volatilizing. Fragments of benzo(k)fluoranthene can also be carried
into waterways where they will be deposited at the bottom and dissolve very slowly. Once the source
has disappeared, the adsorbed benzo(k)fluoranthene will take a very long time to disappear, being
released in its gaseous or dissolved forms. The resulting plumes (gaseous or dissolved) will be
relatively small in size.
Benzo(k)fluoranthene should be handled with care, as it is toxic.
Benzo(k)fluoranthene is a polycyclic aromatic hydrocarbon (PAH). PAHs are a group of
organic compounds that contain two or more benzene rings in their structure. There are more than 100
different PAHs that generally occur as complex mixtures (example, combustion by-products such as soot).
Incomplete combustion of fuels in engines, during coal coking, or when wood is burning (forest
fires, wood stoves) produces PAHs. PAHs are also constituents of petroleum and coal, and they are
more present in some of their derivatives like tars and asphalt. The wood preservative industry
(example, creosote), aluminum smelters using Soderberg electrodes, and hazardous waste disposal sites
are further contributors of anthropogenic PAHs to the environment.
Benzo(k)fluoranthene, like most individual PAHs, has very limited or no known uses, except as
reagents in biochemical or cancer research. Benzo(k)fluoranthene is more likely to be found mixed
with other PAHs in commercial products like coal tar, coal tar pitch, creosote, bitumen and asphalt.
Coal tar is used as a fuel in the steel industry, distilled to give coal tar pitch and creosote, and
has been used in the clinical treatment of skin disorders such as eczema and dermatitis. Coal tar
pitch is used primarily as a binder for aluminum smelting electrodes, but is also used in roofing,
surface coatings and a variety of other applications. Creosote is used to preserve wood for railroad
ties, marine pilings and telephone poles. Some creosote products are also used as a fuel by steel
production. Bitumen and asphalt are used for paving roads, for sound- and water-proofing, and
Agency for Toxic Substances and Disease Registry (ATSDR). 1995. Toxicological
Profile for Polycyclic Aromatic Hydrocarbons (PAHs). U.S. Department of Health and Human
Services, Public Health Service, Georgia, USA.
(Viewed December 2013)
Canadian Council of Ministers of the Environment. 1999. Canadian Water Quality Guidelines for
the Protection of Aquatic Life: Polycyclic Aromatic Hydrocarbons (PAHs). In: Canadian
Environmental Quality Guidelines. Canadian Council of Ministers of the Environment, Manitoba,
Canada. (Viewed December 2013).
Montgomery, John H. 2007. Groundwater Chemicals, Desk Reference, Fourth Edition, CRC
Press, Taylor and Francis Group, Florida, USA.
National Toxicology Program. 2005. Report on Carcinogens, Twelfth Edition: Substance Profile of
Polycyclic Aromatic Hydrocarbons. U.S. Department of Health and Human Services, Public Health
Services, USA.(PDF, 256KB) (Viewed December 2013)